The Role Of Nano-Alumina Particles In Enhancing Asphalt Binder Rheological Properties
DOI:
https://doi.org/10.23918/eajse.v11i2p7Keywords:
Asphalt Binder, Nanomaterial, Nanotechnology, Nano-Alumina, Rheological PropertiesAbstract
Traditional asphalt binders face significant challenges such as aging, temperature susceptibility, and fatigue cracking, which adversely impact highway maintenance and rehabilitation. Modern road networks also face emerging challenges such as increased traffic loads, climate change-induced temperature extremes, and in return, the need for more sustainable and eco-friendly materials to reduce environmental impact is essential. Aging reduces the binder's flexibility, increasing the likelihood of pavement cracking under traffic loads. Temperature susceptibility leads to rutting at high temperatures and thermal cracking in cold conditions, while fatigue cracking compromises the structural integrity of roads under repeated loading. These issues result in higher maintenance costs, reduced infrastructure durability, and potential safety risks for road users. Addressing these challenges is critical to developing sustainable, cost-effective, and safe road networks. Researchers have explored innovative solutions, including incorporating nanomaterials into modified asphalt binders alongside additives like rubbers and polymers. This study investigates the direct integration of nano-alumina into a 60/70 penetration grade asphalt binder without additional additives. Using a high-shear mixer, nano-alumina was incorporated at varying concentrations (2%, 4%, 6%, and 8% by weight). Conventional and rheological tests revealed that the nano-modified binder exhibited enhanced temperature susceptibility, improved overall viscoelastic properties, increased stiffness, better ageing resistance, and improved performance at low temperatures. For example, penetration improved up to 30% for 6% nano content and temperature susceptibility, reaching up to 35% in some contents
References
[1] M. Arabani, M. Sadeghnejad, J. Haghanipour, and M. H. Hassanjani, "The influence of rice bran oil and nano-calcium oxide into bitumen as sustainable modifiers," Case Studies in Construction Materials, vol. 21, p. e03458, 2024/12/01/ 2024.https://doi.org/10.1016/j.cscm.2024.e03458
[2] C. E. Carraher Jr, Seymour/Carraher's polymer chemistry. CRC press, 2007.
[3] R. N. Hunter, A. Self, J. Read, and E. Hobson, The shell bitumen handbook. Ice Publishing London, UK:, 2015.
[4] A. S. Mohammad Asib, R. Rahman, P. Romero, M. P. Hoepfner, and A. Mamun, "Physicochemical characterization of short and long-term aged asphalt mixtures for low-temperature performance," Construction and Building Materials, vol. 319, p. 126038, 2022/02/14/ 2022.https://doi.org/10.1016/j.conbuildmat.2021.126038
[5] M. Porto, P. Caputo, V. Loise, S. Eskandarsefat, B. Teltayev, and C. Oliviero Rossi, "Bitumen and Bitumen Modification: A Review on Latest Advances," Applied Sciences, vol. 9, no. 4, p. 742, 2019. https://doi.org/10.3390/app9040742
[6] J. Teizer, M. Venugopal, W. Teizer, and J. Felkl, "Nanotechnology and Its Impact on Construction: Bridging the Gap Between Researchers and Industry Professionals," Journal of Construction Engineering and Management, vol. 138, pp. 594-604, 05/01 2012. https://doi.org/10.1061/(ASCE)CO.1943-7862.0000467
[7] J. M. L. Crucho, J. M. C. d. Neves, S. D. Capitão, and L. G. d. Picado-Santos, "Mechanical performance of asphalt concrete modified with nanoparticles: Nanosilica, zero-valent iron and nanoclay," Construction and Building Materials, vol. 181, pp. 309-318, 2018/08/30/ 2018.https://doi.org/10.1016/j.conbuildmat.2018.06.052
[8] H. Ezzat, S. El-Badawy, A. Gabr, E.-S. I. Zaki, and T. Breakah, "Evaluation of Asphalt Binders Modified with Nanoclay and Nanosilica," Procedia Engineering, vol. 143, pp. 1260-1267, 2016/01/01/ 2016.https://doi.org/10.1016/j.proeng.2016.06.119
[9] N. Amini and P. Hayati, "Effects of CuO nanoparticles as phase change material on chemical, thermal and mechanical properties of asphalt binder and mixture," Construction and Building Materials, vol. 251, p. 118996, 2020/08/10/ 2020.https://doi.org/10.1016/j.conbuildmat.2020.118996
[10] H. J. Kadhim, A. Modarres, and S. Al-Busaltan, "Rheological and microstructural properties of nano-composite bitumen modified by nano-alumina and low-SBS content," Case Studies in Construction Materials, vol. 20, p. e03244, 2024/07/01/ 2024.https://doi.org/10.1016/j.cscm.2024.e03244
[11] M. Mousavi, S. Aldagari, and E. H. Fini, "Adsorbing Volatile Organic Compounds within Bitumen Improves Colloidal Stability and Air Quality," ACS Sustainable Chemistry & Engineering, vol. 11, no. 26, pp. 9581-9594, 2023/07/03 2023. https://doi.org/10.1021/acssuschemeng.3c00539
[12] A. Zare-Shahabadi, A. Shokuhfar, and S. Ebrahimi-Nejad, "Preparation and rheological characterization of asphalt binders reinforced with layered silicate nanoparticles," Construction and Building Materials, vol. 24, no. 7, pp. 1239-1244, 2010/07/01/ 2010.https://doi.org/10.1016/j.conbuildmat.2009.12.013
[13] L. Zhang, X. Gao, W. Wang, H. Wang, and K. Zheng, "Laboratory Evaluation of Rheological Properties of Asphalt Binder Modified by Nano-TiO2/CaCO3," Advances in Materials Science and Engineering, vol. 2021, p. 5522025, 2021/02/12 2021. https://doi.org/10.1155/2021/5522025
[14] T. Gunay, "Investigation of physical properties of base and SBS modified bitumens by rheological test methods," Revista de la Construcción. Journal of Construction, vol. 21, no. 2, pp. 281-294, 08/31 2022. https://doi.org/10.7764/RDLC.21.2.281
[15] W. Wang, Y. Cheng, G. Tan, Z. Liu, and C. Shi, "Laboratory investigation on high- and low-temperature performances of asphalt mastics modified by waste oil shale ash," Journal of Material Cycles and Waste Management, vol. 20, pp. 1710–1723, 04/23 2018. https://doi.org/10.1007/s10163-018-0737-2
[16] S. G. Jahromi and A. Khodaii, "Effects of nanoclay on rheological properties of bitumen binder," Construction and Building Materials, vol. 23, no. 8, pp. 2894-2904, 2009/08/01/ 2009.https://doi.org/10.1016/j.conbuildmat.2009.02.027
[17] J. Crucho, L. Picado-Santos, J. Neves, and S. Capitão, "A Review of Nanomaterials’ Effect on Mechanical Performance and Aging of Asphalt Mixtures," Applied Sciences, vol. 9, no. 18, p. 3657, 2019. https://doi.org/10.3390/app9183657
[18] H. Yao et al., "Properties and Chemical Bonding of Asphalt and Asphalt Mixtures Modified with Nanosilica," Journal of Materials in Civil Engineering, vol. 25, 09/22 2012. https://doi.org/10.1061/(ASCE)MT.1943-5533.0000690
[19] N. Baldino, D. Gabriele, F. R. Lupi, C. Oliviero Rossi, P. Caputo, and T. Falvo, "Rheological effects on bitumen of polyphosphoric acid (PPA) addition," Construction and Building Materials, vol. 40, pp. 397-404, 2013/03/01/ 2013.https://doi.org/10.1016/j.conbuildmat.2012.11.001
[20] F. Xiao, A. N. Amirkhanian, and S. N. Amirkhanian, "Influence of Carbon Nanoparticles on the Rheological Characteristics of Short-Term Aged Asphalt Binders," Journal of Materials in Civil Engineering, vol. 23, no. 4, pp. 423-431, 2011. https://doi.org/doi:10.1061/(ASCE)MT.1943-5533.0000184
[21] S.-J. Lee, S. N. Amirkhanian, K. Shatanawi, and K. W. Kim, "Short-term aging characterization of asphalt binders using gel permeation chromatography and selected Superpave binder tests," Construction and Building Materials, vol. 22, no. 11, pp. 2220-2227, 2008/11/01/ 2008.https://doi.org/10.1016/j.conbuildmat.2007.08.005
[22] S. S. Galooyak, B. Dabir, A. E. Nazarbeygi, and A. Moeini, "Rheological properties and storage stability of bitumen/SBS/montmorillonite composites," Construction and Building Materials, vol. 24, no. 3, pp. 300-307, 2010/03/01/ 2010.https://doi.org/10.1016/j.conbuildmat.2009.08.032
[23] R. He, S. Wu, X. Wang, Z. Wang, and H. Chen, "Temperature Sensitivity Characteristics of SBS/CRP-Modified Bitumen after Different Aging Processes," (in eng), Materials (Basel), vol. 11, no. 11, Oct 30 2018. https://doi.org/10.3390/ma11112136
[24] F. Xiao, A. N. Amirkhanian, and S. N. Amirkhanian, "Long-term ageing influence on rheological characteristics of asphalt binders containing carbon nanoparticles," International Journal of Pavement Engineering, vol. 12, no. 6, pp. 533-541, 2011/12/01 2011. https://doi.org/10.1080/10298436.2011.560267
[25] B. Karki, Effect of nanomaterials on binder and mix performance. The University of North Dakota, 2017.
[26] G. Cheraghian, M. P. Wistuba, S. Kiani, A. R. Barron, and A. Behnood, "Rheological, physicochemical, and microstructural properties of asphalt binder modified by fumed silica nanoparticles," Scientific Reports, vol. 11, no. 1, p. 11455, 2021/06/01 2021. https://doi.org/10.1038/s41598-021-90620-w
[27] I. A. Abdalfattah, W. S. Mogawer, and K. Stuart, "Quantification of the degree of blending in hot-mix asphalt (HMA) with reclaimed asphalt pavement (RAP) using Energy Dispersive X-Ray Spectroscopy (EDX) analysis," Journal of Cleaner Production, vol. 294, p. 126261, 2021/04/20/ 2021.https://doi.org/10.1016/j.jclepro.2021.126261
[28] Y. Jiang, X. Gu, Z. Zhou, F. Ni, and Q. Dong, "Laboratory Observation and Evaluation of Asphalt Blends of Reclaimed Asphalt Pavement Binder with Virgin Binder using SEM/EDS," Transportation Research Record, vol. 2672, no. 28, pp. 69-78, 2018. https://doi.org/10.1177/0361198118782023
[29] X. Zhu, Y. Yuan, L. Li, Y. Du, and F. Li, "Identification of interfacial transition zone in asphalt concrete based on nano-scale metrology techniques," Materials & Design, vol. 129, pp. 91-102, 2017/09/05/ 2017.https://doi.org/10.1016/j.matdes.2017.05.015
[30] P.-C. Lin, S. Lin, P. C. Wang, and R. Sridhar, "Techniques for physicochemical characterization of nanomaterials," Biotechnology Advances, vol. 32, no. 4, pp. 711-726, 2014/07/01/ 2014.https://doi.org/10.1016/j.biotechadv.2013.11.006
[31] A. H. Albayati, M. J. Al-Kheetan, M. M. Moudhafar, and A. M. Mohammed, "Nanomaterials in asphalt cement: Exploring their single and combined effects on the physical and rheological properties," Results in Engineering, vol. 24, p. 103225, 2024/12/01/ 2024.https://doi.org/10.1016/j.rineng.2024.103225
[32] Z. Iqbal, M. S. Mir, and B. Mohanty, "High- and Intermediate-Temperature Performance of Crumb Rubber-Nano-Alumina-Modified Asphalt Binder," in Transportation Research, Singapore, 2024, pp. 257-276: https://doi.org/10.1007/978-981-99-6090-3_21
[33] R. A. Al-Mansob et al., "The performance of epoxidised natural rubber modified asphalt using nano-alumina as additive," Construction and Building Materials, vol. 155, pp. 680-687, 2017. https://doi.org/10.1016/j.conbuildmat.2017.08.106
[34] S. I. A. Ali, I. Amiruddin, K. M. Rehan, Y. N. I. Md, A.-M. R. A., and E. and Aburkaba, "Performance evaluation of Al2O3 nanoparticle-modified asphalt binder," Road Materials and Pavement Design, vol. 18, no. 6, pp. 1251-1268, 2017/11/02 2017. https://doi.org/10.1080/14680629.2016.1208621
[35] S. I. A. Ali, A. Ismail, N. I. M. Yusoff, N. A. Hassan, and A. N. H. Ibrahim, "Characterization of the performance of aluminum oxide nanoparticles modified asphalt binder," Jurnal Teknologi, vol. 78, no. 4, 2016. https://doi.org/10.11113/jt.v78.8003
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